DOPO (9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide)
CAS # 35948-25-5

9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide (DOPO) is a high-performance, halogen-free flame retardant widely used in epoxy resins, engineering plastics, and specialty polymer systems.
Description:
DOPO is a halogen-free and phosphorus-based flame-retardant used in engineering plastics, epoxy resins, and specialty polymer systems. It is known for its excellent thermal stability and compatibility with polymer matrices. DOPO enhances fire resistance while maintaining mechanical and electrical properties. DOPO is used to meet stringent fire safety standards in electronics, automotive, and industrial applications without compromising performance.
General Properties:
Molecular Formula: C₁₂H₉O₂P
Appearance: White to off-white crystalline solid
Melting Point: ~115–120 °C
Solubility: Slightly soluble in water; soluble in organic solvents
Applications:
Epoxy Resin Flame Retardant
Used as a reactive or additive flame retardant in epoxy systems for electronics, laminates, and structural composites.
Plastics & Polymers
Incorporated into polyamides, polyesters, and other high-performance polymers to improve fire resistance.
Electronics & Electrical Materials
Helps meet UL-94 and other fire safety requirements for circuit boards, connectors, and housings.
Reactive Flame-Retardant Intermediates
Serves as a building block for DOPO derivatives used in advanced polymer systems.
Coatings & Adhesives
Improves flame resistance in protective coatings and specialty adhesive formulations.
Advantages:
Halogen-Free Flame Retardancy: Supports environmentally preferred flame-retardant systems without halogenated additives.
Excellent Thermal Stability: Performs well in high-temperature polymer processing environments.
Reactive Functionality: Can chemically bond into polymer matrices, reducing migration and improving durability.
Maintains Mechanical Properties: Provides fire protection without significantly compromising strength or electrical performance.
Versatile Polymer Compatibility: Suitable for epoxies, polyamides, polyesters, and specialty resins.
Safety & Handling:
DOPO should be handled using standard industrial chemical safety practices.
Dust may cause mild eye, skin, or respiratory irritation
Avoid inhalation of airborne particles
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